99015-07-3Relevant academic research and scientific papers
A CONFIGURATION-RETAINING α,β-DIOL TO 1,4-DIOXANE CONVERSION
Hosten, N. G. C.,Tavernier, D.,Anteunis, M. J. O.
, p. 183 - 186 (2007/10/02)
Cis-Perhydronaphthalene-2,3-diol treated with ethyl diazoacetate/rhodium(II) pivalate gives the mono-O-alkylation product which cyclizes readily to the lactone(dioxanone)- Photochemical deoxygenation with trichlorosilane affords the dioxane derivative perhydro-1,4-dioxaanthracene.
