99031-02-4Relevant academic research and scientific papers
PREPARATION OF PENTAMETHYLCYCLOPENTADIENYL-DIALKYLNITROSYLIRON COMPLEXES
Diel, Bruce N.
, p. 257 - 262 (2007/10/02)
The dimer 2 has been prepared by octane reflux of 2 under a NO atmosphere.Oxidative cleavage of the dimer with iodine yields (CH3)5C5Fe(NO)I2.Alkylation with two equivalents of RLi or RMgX (R = CH3, CH2C6H5, or CH2SC6H5) leads to the dialkyl derivatives in good yields.All compounds are new and have been characterized by elemental analyses, IR, mass 1H and 13C NMR spectra.
