99049-59-9Relevant academic research and scientific papers
THE SYNTHESIS OF 2-AZIDO C-GLYCOSYL SUGARS
Bertozzi, Carolyn,Bednarski, Mark D.
, p. 3109 - 3112 (2007/10/02)
2-Azido C-glycosyl sugars can be prepared by the Lewis acid catalyzed addition of alkyl silanes to the nitrate glycosides of 2-azido sugars.The products are ozonized to the corresponding aldehydes for further elaboration.
Glycosylphosphonates of 2-Amino-2-deoxy-aldoses. Synthesis of a Phosphonate Analogue of Lipid X
Briner, Karin,Vasella, Andrea
, p. 1341 - 1356 (2007/10/02)
A preparation of glycosylphosphonates (27, 28, 36, 38, and 39) from 2-azido-2-deoxy-glycoses (26, 35, and 37) and the synthesis of the non-isosteric phosphonate analogue 3a of lipid X (2) are described.The 2-azido group was introduced by azidonitration.Tr
