99060-54-5Relevant academic research and scientific papers
Clean preparation of S-thiocarbamates with in situ generated hydroxide in 2-methyltetrahydrofuran
Bao, Wen-Hu,Wang, Zheng,Tang, Xiao,Zhang, Yun-Fu,Tan, Jia-Xi,Zhu, Qin,Cao, Zhong,Lin, Ying-Wu,He, Wei-Min
supporting information, p. 2259 - 2262 (2019/07/30)
A simple and clean protocol for the synthesis of various alkyl and (hetero)aryl S-thiocarbamates was established. The usage of in situ generated hydroxide as both an oxygen source and hydrogen source as well as biomass-derived 2-methyltetrahydrofuran as a
Iodine-catalyzed cross-coupling of isocyanides and thiols for the synthesis of: S -thiocarbamates
Pathare, Ramdas S.,Patil, Vikas,Kaur, Harpreet,Maurya, Antim K.,Agnihotri, Vijai K.,Khan, Shahnawaz,Devunuri, Nagaraju,Sharon, Ashoke,Sawant, Devesh M.
supporting information, p. 6885 - 6888 (2018/10/02)
A novel and efficient metal free, redox-neutral method for the synthesis of secondary thiocarbamates by cross-coupling of readily available thiophenol and isocyanides has been developed. The present methodology exhibits a broad substrate scope with good to excellent yields without an additive/extra oxidant under mild reaction conditions catalyzed by inexpensive iodine as the catalyst.
Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions
Bao, Wen-Hu,Wu, Chao,Wang, Jing-Ting,Xia, Wen,Chen, Ping,Tang, Zilong,Xu, Xinhua,He, Wei-Min
supporting information, p. 7025 - 7029 (2018/10/02)
A simple and practical molecular iodine-mediated method for the efficient construction of thiocarbamates from isocyanides, thiols and water under metal-free and mild conditions has been developed. A variety of thiocarbamates were easily synthesized through this methodology, which has the advantages of simple operation, eco-friendly conditions, good functional group tolerance, and readily accessible raw materials.
Iodide-Catalyzed Synthesis of Secondary Thiocarbamates from Isocyanides and Thiosulfonates
Mampuys, Pieter,Zhu, Yanping,Sergeyev, Sergey,Ruijter, Eelco,Orru, Romano V. A.,Van Doorslaer, Sabine,Maes, Bert U. W.
, p. 2808 - 2811 (2016/07/06)
A new method for the synthesis of secondary thiocarbamates from readily available isocyanides and thiosulfonates with broad functional group tolerance is reported. The reaction proceeds under mild reaction conditions in isopropanol and is catalyzed by inexpensive sodium iodide.
