99063-92-0Relevant articles and documents
Hexagonal packing of cis,cis-cyclo-hexane-1,3,5-tricarboxamide
Saha, Binoy K.
, p. o591-o593 (2007)
The title compound, C9H15N3O3, which has crystallographically imposed threefold symmetry, crystallizes as a hexa-gonal columnar structure. The crystal structure is stabilized by a less common amide-amide synthon, where one amide group is hydrogen bonded t
A flexible solution to anion transport: Powerful anionophores based on a cyclohexane scaffold
Cooper, James A.,Street, Steven T. G.,Davis, Anthony P.
, p. 5609 - 5613 (2014/06/10)
Transmembrane anion carriers (anionophores) have potential for biological activity, including the treatment of channelopathies such as cystic fibrosis. A new family of anionophores has been synthesized, in which three thiourea groups are mounted on a cyclohexane-based scaffold. Though conceptually related to earlier polycyclic systems, these molecules are simpler and far more accessible. Preorganization is somewhat reduced compared to earlier systems, and anion affinities are correspondingly lower. However, transport activities set new records. This surprising performance suggests a role for controlled flexibility in the design of transmembrane anion carriers. Speedy shuttling: New anionophores were developed which are simpler and far more accessible than conceptually related earlier systems. They are also less preorganized and anion affinities are lower (as expected), but transport activities set new records. This surprising performance suggests a role for controlled flexibility in the design of transmembrane anion carriers.
Anionic polymerization of an acrylonitrile trimer studied by photoelectron spectroscopy
Fukuda, Yuji,Ichihashi, Masahiko,Terasaki, Akira,Kondow, Tamotsu,Osoda, Kazuhiko,Narasaka, Koichi
, p. 7180 - 7184 (2007/10/03)
Anionic polymerization of an acrylonitrile trimer was discussed. Photoelectron spectrum was studied which is produced by electron impact on an acrylonitrile cluster. Results showed that the formation of stereoisomer is determined by the energetics and the entropy requirement of the reaction system.