99096-90-9Relevant articles and documents
Chelation- and Non-Chelation-Controlled Additions to 2-O-Benzyl-3-O-(tert-butyldimethylsilyl)glyceraldehyde
Reetz, Manfred T.,Kesseler, Kurt
, p. 5434 - 5436 (2007/10/02)
2-O-Benzyl-3-O-(tert-butyldimethylsilyl)glyceraldehyde, prepared from 1,3:4,5-di-O-benzylidenemannitol, undergoes chelation- or non-chelation-controlled Grignard-type and aldol additions, depending upon the nature of the organometallic reagent used (TiCl4/Me2Zn, TiCl4/allylsilane, SnCl4/enol silane, RTi(OCHMe2)3, and BF3/allylsilane).