99142-50-4Relevant academic research and scientific papers
Construction of Five-Membered Rings by Michael Addition-Radical Cyclization
Clive, Derrick L.J.,Boivin, Taryn L.B.,Angoh, A. Gaeetan
, p. 4943 - 4953 (2007/10/02)
Enamines react with Michael acceptors 8-10 to produce ketones that, on treatment with lithium acetylides, afford hydroxy acetylenes 3.These compounds then undergo radical cyclization when treated with triphenyltin hydride and AIBN.The products 6 are forme
2-(Phenylseleno)prop-2-enenitrile: a Three-carbon Unit for Radical Cyclization
Angoh, A. Gaaetan,Clive, Derrick L. J.
, p. 941 - 942 (2007/10/02)
Successive reaction of enamines with 2-(phenylseleno)prop-2-enenitrile, lithium phenylacetylide, and triphenyltin hydride serves to generate carbocycles by a process of radical ring closure.
