99188-19-9Relevant academic research and scientific papers
NOUVEAUX DECONTAMINANTES. DESTRUCTION OXYDATIVE D'UN SILIMI DE L'YPERITE: LE PHENYL-2 CHLORO-2' DIETHYLSULFURE PAR LE MONOPERSULFATE DE POTASSIUM
Leblanc, Andre,Fosset, Laurent,Magnaud, Gilbert,Delmas, Gerard,Desgranges, Michel,et al.
, p. 141 - 146 (2007/10/02)
The reaction of potassium monopersulfate (CUROX or OXONE) with 2-phenyl 2'-chloro diethylsulfide PhCH2CH2SCH2CH2Cl goes to completion in a very short time.The intermediate chlorinated sulfone PhCH2CH2SO2CH2CH2Cl leads to the phenethylvinylsulfone PhCH2CH2SO2CH=CH2 by HCl elimination. Key words: decontamination; potassium monopersulfate; yperite.
NOUVEAUX DECONTAMINANTS. DESTRUCTION DE TOXIQUES ORGANOPHOSPHORES OU SOUFRES PAR DES PERACIDES MONO-, BI- ET TRICYCLIQUES SATURES
Lion, C.,Hedayatullah, M.,Bauer, P.,Boukou-Poba, J. P.,Charvy, C.,et al.
, p. 249 - 256 (2007/10/02)
New peroxycarboxylic and peroxyacetic acids have been tested for the destruction of some organophosphorus compounds and mustards.The peroxyacids used have monocyclic, bicyclic or tricyclic structures.These are very reactive against paraoxon or HD and the addition of certain surfactants enhances the reaction rate.Very short half-live times are obtained with these compounds.
NOUVEAUX DECONTAMINANTS. DESTRUCTION DU PARAOXON ET D'UN SIMILI DE L'YPERITE PAR QUELQUES ACIDES HYDROXAMIQUES
Lion, C.,Hedayatullah, M.,Bauer, P.,Boukou-Poba, J. P.,Charvy, C.,et al.
, p. 617 - 621 (2007/10/02)
A new series of hydroxamic acids 1-4 has been used in the destruction of paraoxon (O,O-diethyl O-paranitrophenylphosphate) and a mustard-related compound (2-chloro 2'-phenyl diethylsulfide).These hydroxamic acids are N-alkyl substituted isonicotinhydroxamic acid 1, and quinolone derivatives 2 norbornyl- and adamantylhydroxamic acids 3 and 4.The latter are very reactive and the addition of certain surfactants enhances the rate of the reaction.Very short half-lives are obtained with these compounds.
