99196-14-2

Basic information

• Product Name: 3-ethoxy-6-isobutylcyclohex-2-en-1-one
• Synonyms: 3-ethoxy-6-isobutylcyclohex-2-en-1-one
• CAS NO: 99196-14-2
• Molecular Weight: 196.29
• Mol File: 99196-14-2.mol

Chemical Properties

• CAS DataBase Reference: 3-ethoxy-6-isobutylcyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-ethoxy-6-isobutylcyclohex-2-en-1-one(99196-14-2)
• EPA Substance Registry System: 3-ethoxy-6-isobutylcyclohex-2-en-1-one(99196-14-2)

Safety Data

• Hazardous Substances Data: 99196-14-2(Hazardous Substances Data)

Upstream product

• 513-38-2 Isobutyl iodide 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 1065010-54-9 C₁₂H₁₈O₂ 

Downstream Products

• 1026069-25-9 3-Ethoxy-6-isobutyl-1-methyl-cyclohex-2-enol 
• 147120-48-7 3-Methyl-4-isobutyl-2-cyclohexen-1-one 

Relevant articles and documents

Highly Selective Hydrogenation of C═C Bonds Catalyzed by a Rhodium Hydride

Under mild conditions (room temperature, 80 psi of H2) Cp*Rh(2-(2-pyridyl)phenyl)H catalyzes the selective hydrogenation of the C═C bond in α,β-unsaturated carbonyl compounds, including natural product precursors with bulky substituents in the β position and substrates possessing an array of additional functional groups. It also catalyzes the hydrogenation of many isolated double bonds. Mechanistic studies reveal that no radical intermediates are involved, and the catalyst appears to be homogeneous, thereby affording important complementarity to existing protocols for similar hydrogenation processes.

Pyrazolopyridine cycloalkanones and process for their preparation

Novel tetrahydropyrazolo-[3,4-b]quinolinones, cyclopenta[b]pyrazolo-[4,3-e]pyridinones and cyclohepta[b]-pyrazolo[4,3-e]pyridinones, useful as anxiolytics having reduced side effects, are disclosed, including methods of preparation, pharmaceutical compositions containing them and intermediates used in their preparation.