99260-84-1Relevant academic research and scientific papers
Regioselective and Stereoselective Nucleophilic Addition to Electrophilic Vinylcyclopropanes
Burgess, Kevin
, p. 2046 - 2051 (2007/10/02)
Palladium(0) complexes catalyze ring opening of 1,1-diactivated 2-vinylcyclopropanes 2 with concomitant addition of a carbon nucleophile.The reaction is extremely regioselective and stereoselective in that the alkylation occurs syn to the cyclopropane bond being cleaved in bicyclic system (n = 3, 4).
CONJUGATE NUCLEOFHILIC RING OPENING OF ACTIVATED VINYLCYCLOPROPANES FACILITATED BY HOMOGENOUS PALLADIUM CATALYSIS
Burgess, Kevin
, p. 3049 - 3052 (2007/10/02)
1,1-Diactivated-2-vinylcyclopropanes (1) add carbon nucleophiles (2) regiospecifically in a conjugate sense in the presence of a catalytic amount of a zerovalent palladium complex.
