99260-87-4Relevant articles and documents
Regioselective and Stereoselective Nucleophilic Addition to Electrophilic Vinylcyclopropanes
Burgess, Kevin
, p. 2046 - 2051 (2007/10/02)
Palladium(0) complexes catalyze ring opening of 1,1-diactivated 2-vinylcyclopropanes 2 with concomitant addition of a carbon nucleophile.The reaction is extremely regioselective and stereoselective in that the alkylation occurs syn to the cyclopropane bond being cleaved in bicyclic system (n = 3, 4).