99277-12-0

Basic information

• Product Name: 4-Bromo-benzoic acid 2-((1R,2R,4R)-1-methyl-5-oxo-bicyclo[2.1.1]hex-2-yl)-ethyl ester
• CAS NO: 99277-12-0
• Molecular Weight: 337.213
• Mol File: 99277-12-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Bromo-benzoic acid 2-((1R,2R,4R)-1-methyl-5-oxo-bicyclo[2.1.1]hex-2-yl)-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Bromo-benzoic acid 2-((1R,2R,4R)-1-methyl-5-oxo-bicyclo[2.1.1]hex-2-yl)-ethyl ester(99277-12-0)
• EPA Substance Registry System: 4-Bromo-benzoic acid 2-((1R,2R,4R)-1-methyl-5-oxo-bicyclo[2.1.1]hex-2-yl)-ethyl ester(99277-12-0)

Safety Data

• Hazardous Substances Data: 99277-12-0(Hazardous Substances Data)

Upstream product

• 98049-45-7 (1'R,2'R)-2-(2'-bromomethyl-2'-methyl-3'-methylenecyclopentyl)ethanoic acid 
• 99277-07-3 (2R,3R)-2-Bromomethyl-3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2-methyl-cyclopentanone 
• 99277-10-8 (1R,2R,4R)-2-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-methyl-bicyclo[2.1.1]hexan-5-one 
• 99277-06-2 (2R,3R)-2-Bromomethyl-3-(2-hydroxy-ethyl)-2-methyl-cyclopentanone 
• 99277-05-1 (1R,2R)-2-Bromomethyl-1-(2-hydroxyethyl)-2-methyl-3-methylenecyclopentane 
• 99277-11-9 (1R,2R,4R)-2-(2-Hydroxy-ethyl)-1-methyl-bicyclo[2.1.1]hexan-5-one 
• 586-75-4 4-chlorobenzoyl chloride 

Relevant articles and documents

A formal enantiospecific synthesis of California red scale pheromone

Cleavage of α,α-disubstituted β-bromoketone intermediates derived from (+)-camphor forms the basis of an alternative enantiospecific synthesis of (Z)-3-methyl-6-isopropenyl-3,9-decadien-1-yl acetate (1), one of the sex pheromones of the female California red scale, Aonidiella aurantii (Maskell).