99315-79-4

Upstream product

• 109917-95-5 2-diphenyl-t-butylsiloxymethyl-6-methoxycarbonyl-3-oxabicyclo<3.3.0>octan-7-one 
• 99315-78-3 (2S,3R,4S)-2-diphenyl-t-butylsiloxymethyl-3,4-bis(methoxycarbonylmethyl)tetrahydrofuran 
• 99315-76-1 (5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone 
• 99808-03-4 (1R,6S,7S)-7-diphenyl-t-butylsiloxymethyl-8-oxabicyclo-<4.3.0>non-3-ene 
• 99315-77-2 (4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene 
• 109917-94-4 [(2S,3S,4R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-4-carboxymethyl-tetrahydro-furan-3-yl]-acetic acid 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 99315-75-0 (-)-5-O-(diphenyl-t-butylsilyl)-2,3-O-(thiocarbonyl)-D-ribono-1,4-lactone 
• 99333-00-3 (+)-(1R,6S,7S)-7-diphenyl-t-butylsiloxymethyl-8-oxabicyclo-<4.3.0>non-3-en-9-one 
• 92512-33-9 (3R,4S,5R)-5-((tert-butyldiphenylsilyloxy)methyl)-3,4-dihydroxydihydrofuran-2(3H)-one 

Downstream Products

• 109775-01-1 5-[(1S,3aR,6aS)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-tetrahydro-cyclopenta[c]furan-(5E)-ylidene]-pentanoic acid 

Relevant academic research and scientific papers

Chiral Oxabicyclic Systems from Ribonolactone

We describe the synthesis of (-)-5-O-diphenyl-t-butylsiloxymethyl-5H-furan-2-one (4) from D-ribonolactone; conversion of this chiral butenolide into (+)-(1R,6S,7S)-7-diphenyl-t-butylsiloxymethyl-8-oxabicyclonon-3-en-9-one (10) (by means of a Diels-

Chiral Bicycles from Ribonolactone

The preparation of the chiral butenolide (4b) is described, together with its use in annulation reactions yielding stereochemically defined bicyclo, , and ring systems; the synthetic utility of these species is indicated.