99328-22-0Relevant academic research and scientific papers
[ClP(μ-PMes?)]2 - A versatile reagent in phosphorus chemistry
Bresien, Jonas,Schulz, Axel,Villinger, Alexander
, p. 601 - 604 (2016)
The synthesis and some key reactions of the cyclotetraphosphane [ClP(μ-PMes?)]2 (2, Mes? = 2,4,6-tri-tert-butylphenyl) with Lewis acids and reducing agents are discussed. All products were fully characterized, including single crystal X-ray diffraction, spectroscopic methods as well as computational studies.
A Systematic Survey of the Reactivity of Chlorinated N2P2, NP3 and P4 Ring Systems
Bresien, Jonas,Eickhoff, Liesa,Schulz, Axel,Suhrbier, Tim,Villinger, Alexander
supporting information, p. 16311 - 16319 (2019/11/28)
The reactivity of the four-membered NP3 ring system [RN(μ-PCl)2PR] (R=Mes=2,4,6-tri-tert-butylphenyl) towards Lewis acids, Lewis bases, and reducing agents was investigated. Comparisons with the literature-known, analogous cyclic compounds [ClP(μ-NR)]2 (R=Ter=2,6-dimesitylphenyl) and [ClP(μ-PR)]2 (R=Mes*) are drawn, to obtain a better systematic understanding of the reactivity of cyclic NP species. Apart from experimental results, DFT computations are discussed to further the insight into bonding and electronic structure of these compounds.
Synthesis and Structural Characterization of the First Donor-stabilized Phosphanetriylphosphonium Cation: + (Ar* = 2,4,6-But3C6H2)
Romanenko, Vadim D.,Rudzevich, Valentin L.,Rusanov, Eduard B.,Chernega, Alexander N.,Senio, Anna,et al.
, p. 1383 - 1386 (2007/10/02)
Reaction of Ar*P=PNR2 (Ar* = 2,4,6-But3C6H2) with CF3SO3H in the presence of triphenylphospane in CH2Cl2 produces the isolable salt +- which is characterized by X-ray crystallography; the triphenylphosphane ligand of Ar*PP
Photochemie von pentamethylcyclopentadienyl-substituierten Diphosphenen und Phosphaarsenen
Jutzi, P.,Meyer, U.
, p. C18 - C20 (2007/10/02)
Under irradiation dimerization of the diphosphenes Cp*P=PCp* and Cp*P=PR (Cp* = Pentamethylcyclopentadienyl, R = 2,4,6-Tri-t-butylphenyl) and the phosphaarsene Cp*As=PR takes place.Further irradiation leads to homolytic cleavage of Cp*-element bonds.Intramolecular recombination leads to the bicyclic butterfly-compounds P4R2 and P2As2R2.
