99336-63-7Relevant academic research and scientific papers
Thermal Rearrangement of Benzisoxazole- and Naphthisoxazolequinones in Solution and in the Solid State. Stereoselective Synthesis of γ-Cyanomethylidenebutenolides.
Martinez-Diaz, M. Victoria,Rodriguez-Morgade, Salome,Schaefer, Wolfram,Torres, Tomas
, p. 2261 - 2274 (1993)
Readily accessible benzisoxazolequinones 1 undergo thermal induced highly stereoselective rearrangement in solution to afford quantitatively γ-cyanomethylidenebutenolides 3.The transformation can be explained by the formation of a vinylogous nitrene inter
