99377-19-2Relevant academic research and scientific papers
PHOTOCHEMISTRY OF DI(9-ANTHRYL)- AND BENZYL-SUBSTITUTED SILANES AND RELATED COMPOUNDS
Sakurai, Hideki
, p. 205 - 210 (2007/10/02)
By irradiation, both di(9-anthryl)dimethylsilane and germane afforded a new type of intramolecular addition product that underwent quantitative cycloreversion by thermolysis.The photoproduct from the former was converted to a novel naphthotriptycene derivative.A phosphorus analogue, di(9-anthryl)phenylphosphine, however did not undergo the reaction.Photochemical reactions of benzyltrimethylsilane and acyloxymethyl(benzyl)dimethylsilanes (RC(O)OCH2SiMe2CH2Ph: R = CH3 and R = t-Bu) are also reported for the first time.The mechanisms of these new photochemical reactions are discussed.
