99381-85-8Relevant academic research and scientific papers
Diastereoselective Epoxidation of Allylic Phosphine Oxides
Clayden, Jonathan,Collington, Eric W.,Egert, Ernst,McElroy, Andrew B.,Warren, Stuart
, p. 2801 - 2810 (2007/10/02)
Allylic phosphine oxides are epoxidised anti selectively by m-CPBA, but this selectivity can be reversed if the allylic phosphine oxide is also an allylic alcohol.
STEREOSELECTIVE PERACID EPOXIDATION OF ALLYLIC AND δ-HYDROXYALLYLIC DIPHENYLPHOPHINE OXIDES
McElroy, Andrew B.,Warren, Stuart
, p. 2119 - 2122 (2007/10/02)
The title compounds were epoxidised by m-chloroperbenzoic acid with high stereoselectivity induced by the Ph2PO or hydroxyl groups.
