99388-29-1Relevant academic research and scientific papers
Synthesis of a versatile tetrasaccharide of sialyl Le(x) and Le(x) antigens
Chowdhury
, p. 12775 - 12782 (2007/10/03)
Benzyl 4-O-[2,4,6-tri-O-benzyl-3-O-(4-methoxybenzyl)-β-D-galactopyranosyl]2, 3,6-tri-O-benzyl-β-D-glucopyranoside (4) was synthesized from benzyl lactoside (2) via regioselective protection of 3'-OH with 4-methoxybenzyl group. Oxidative deprotection of 4 afforded the valuable acceptor. 5. The trisaccharide 7 was obtained through coupling of 5 and phenyl 2-deoxy-3,4,6-tri-O-acetyl-2-phthalimido-1-thio-β-D-glucopyranoside (6). The desired tetrasaccharide 1 was built up through fucosylation of the benzylidene derivative 11 obtained from 7.
Synthesis of benzyl O-(2-O-methyl-β-D-galactopyranosyl)-(1->3)-2-acetamido-2-deoxy-β-D-glucopyranoside , and its higher saccharide containing and O-(2-O-methyl-β-D-galactopyranosyl)-(1->3)-2-acetamido-2-deoxy-β-D-glucop
Sarkar, Arun K.,Jain, Rakesh K.,Matta, Khushi L.
, p. 33 - 46 (2007/10/02)
Treatment of benzyl O-β-D-galactopyranosyl-(1->3)-2-acetamido-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside with tert-butylchlorodiphenylsilane afforded the 6'-O-tert-butyldiphenylsilyl ether, which was converted into the 3',4'-O-isopropylidene derivat
Glycosyl Imidates, 42.- Selectively Protected Lactose and 2-Azido Lactose, Building Blocks for Glycolipid Synthesis
Jung, Karl-Heinz,Hoch, Monika,Schmidt, Richard R.
, p. 1099 - 1106 (2007/10/02)
Performing regioselective alkylation at 3'-OH of benzyl β-lactoside 1 by the stannylation method we prepared the 3'-OH- and 4'-OH-unprotected lactose derivatives 5 and 10 and the 4'-OH-unprotected lactose derivative 9 containing a different protecting gro
4-O-beta-D-Galactopyranosyl-3-O-methyl-D-glucose: a new synthesis and application to the evaluation of intestinal lactase.
Fernandez-Mayoralas,Martin-Lomas,Villanueva
, p. 81 - 91 (2007/10/02)
4-O-beta-D-Galactopyranosyl-3-O-methyl-D-glucose (1, 3-O-methyl-lactose) has been prepared from benzyl 2,6-di-O-benzyl-4-O-(2,6-di-O-benzyl-3, 4-O-isopropylidene-beta-D-galactopyranosyl)-beta-D-glucopyranoside (5) and from benzyl 2,6-di-O-benzyl-4-O-(2,3,
