99397-05-4

Basic information

• Product Name: Pt(C₆H₅SeCH₂CH₂SeC₆H₅)Cl₂
• CAS NO: 99397-05-4
• Molecular Weight: 606.171
• Mol File: 99397-05-4.mol

Chemical Properties

• CAS DataBase Reference: Pt(C₆H₅SeCH₂CH₂SeC₆H₅)Cl₂(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(C₆H₅SeCH₂CH₂SeC₆H₅)Cl₂(99397-05-4)
• EPA Substance Registry System: Pt(C₆H₅SeCH₂CH₂SeC₆H₅)Cl₂(99397-05-4)

Safety Data

• Hazardous Substances Data: 99397-05-4(Hazardous Substances Data)

Upstream product

• 13869-38-0 bis(acetonitrile)dichloroplatinum(II) 
• 37183-13-4 1,2-bis(phenylselanyl)ethane 

Downstream Products

• 103961-58-6 [Pt((C₆H₅)SeCH₂CH₂Se(C₆H₅))Cl₄] 

Relevant articles and documents

Synthesis, Properties, and Multinuclear Nuclear Magnetic Resonance (1H, 77Se, and 195Pt) Studies on Diselenoether Complexes of Palladium, Platinum, and Rhodium

The synthesis of (M=Pd or Pt; X=Cl, Br, or I) complexes of the diselenoethers, L-L=MeSeCH2CH2SeMe, PhSeCH2CH2SePh, o-C6H4(SeMe)2, cis-MeSeCH=CHSeMe, or MeSeCH2CH2CH2SeMe, is reported.The complexes were characterised by microanalysis, i.r., and electronic spectroscopy, 1H, 77Se, and in some cases 195Pt n.m.r. spectroscopy.The trends in the 77Se chemical shifts and in 1J(PtSe) with invertomer, metal, chelate ring size, and with the trans halide are discussed.The rhodium(III) complexes, , trans-ClO4, and cis-Cl (L'-L'=MeSeCH2CH2SeMe), were similarly characterised, and 77Se chemical shifts and 1J(RhSe) are reported.A ring contribution, dependent upon the chelate ring size, has been identified in the 77Se n.m.r. shifts.