99413-16-8Relevant academic research and scientific papers
Transition metal-free dimerization of alkynes using hypervalent iodine reagents
Sch?rgenhumer, Johannes,Waser, Mario
, p. 1678 - 1680 (2016)
This communication describes the use of hypervalent iodine reagents to facilitate the homo-coupling of terminal alkynes. A variety of different aliphatic and aromatic alkynes were successfully dimerized when using acetoxy-benziodoxole as the activating agent under operationally simple transition metal-free conditions.
A NEW METHOD FOR THE SYNTHESIS OF VINYL- AND DI-ALLENES ASSISTED BY ORGANOALUMINIUM CONPOUNDS
Tolstikov, G. A.,Romanova, T. Yu.,Kuchin, A. V.
, p. 71 - 82 (2007/10/02)
The interactions of organoaluminium reagents with acetates of substituted propargyl alcohols have been considered as the most appropriate method to synthesize allenes.Studies have been carried out on the synthesis of vinyl- and di-allenes, employing both
