99451-09-9Relevant academic research and scientific papers
STUDIES ON SULFENAMIDES. IX. ANODIC OXIDATION OF N-(o-NITROPHENYLTHIO)ALICYCLIC AMINES
Sayo, Hiroteru,Michida, Takashi
, p. 2541 - 2544 (2007/10/02)
Cation radicals generated by anodic oxidation of N-(o-nitrophenylthio)alicyclic amines (morpholine (1), thiomorpholine(tetrahydro-4H-1,4-thiazine) (2), piperidine (3), pyrrolidine (4)) in acetonitrile were studied by cyclic voltammetry (CV) and electron spin resonance spectroscopy (ESR). 2-(o-Nitrophenylthio)indan-1-ol (6) was obtained from the solution after controlled potential electrolysis (CPE) of 1-3 in acetonitrile containing indene (5) and 0.1 M NaClO4 at a glassy carbon anode.The cation radicals produced by CPE of 1-3 attacked 5 to give 6 as a final product.Keywords-anodic oxidation; 2-nitrobenzenesulfenamide; cyclic voltammetry; electron spin resonance; cation radical; indanol 2-substituted; electrophilic substitution
