99474-99-4

Upstream product

• 83379-10-6 1,1,3,3-tetramethyl-5-methylene-2-(1-methylethenyl)cyclohexane 
• 113831-05-3 cis-1-hydroxymethyl-3,3,5,5-tetramethyl-4-(1-methylethenyl)cyclohexane 

Downstream Products

• 99510-30-2 trans-3,3,5,5-tetramethyl-4-(1-methylethenyl)-1-cyclohexanecarbaldehyde 
• 113831-04-2 trans-1-hydroxymethyl-3,3,5,5-tetramethyl-4-(1-methylethen)cyclohexane 

Relevant academic research and scientific papers

Regio- and Stereoselective Transformations of 3,3,5,5-Tetramethylcyclohexane Derivatives Oxygenations, Annulations, and SN2'-Reactions

Hydroboration of TM-Δ1,7-methadiene (4) (TM = tetramethyl) with 9-BBN gave TM-cis-shisool (cis-5), which was converted into TM-trans-shisool (trans-5) via the aldehyde cis-7, base-catalyzed epimerization to trans-7, and finally LiAlH4 reduction