99482-54-9Relevant academic research and scientific papers
REACTION OF THE NITROGEN-CONTAINING HETEROANALOGS OF ACETALS WITH TRIETHYLSILANE
Khlebnikova, T. D.,Mel'nitskii, I. A.,Kiladze, T. K.,Kantor, E. A.,Popov, Yu. N.,Rakhmankulov, D. L.
, p. 1532 - 1537 (2007/10/02)
The reaction of 1,3-oxaazacycloalkanes with triethylsilane in the presence of a nickel catalyst and zinc halides was investigated.The new compounds of the triethylsilyloxy(dialkylamino)alkane type, i.e., products from the chemospecific cleavage of the heterocycle at the C2-O bond, were isolated and characterized.It was established that triethylsilane can cleave the C-N bond in acyclic aminals with the formation of triethyl(dialkylamino)silanes and tertiary amines.
