99484-20-5Relevant articles and documents
Base-Mediated Generation of Ketenimines from Ynamides: Direct Access to Azetidinimines by an Imino-Staudinger Synthesis
Romero, Eugénie,Minard, Corinne,Benchekroun, Mohamed,Ventre, Sandrine,Retailleau, Pascal,Dodd, Robert H.,Cariou, Kevin
, p. 12991 - 12994 (2017)
Ynamides were used as precursors for the in situ generation of highly reactive ketenimines that could be trapped with imines in a [2+2] cycloaddition. This imino-Staudinger synthesis led to a variety of imino-analogs of β-lactams, namely azetidinimines (2
Studies on the interaction of isocyanides with imines: Reaction scope and mechanistic variations
Ghashghaei, Ouldouz,Manna, Consiglia Annamaria,Vicente-Garcia, Esther,Reves, Marc,Lavilla, Rodolfo
supporting information, p. 12 - 17 (2014/01/23)
The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-me