99485-10-6

Basic information

• Product Name: 1-phenylthio-2-chloroethyl ethyl sulfone
• Synonyms: 1-phenylthio-2-chloroethyl ethyl sulfone
• CAS NO: 99485-10-6
• Molecular Weight: 264.797
• Mol File: 99485-10-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-phenylthio-2-chloroethyl ethyl sulfone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylthio-2-chloroethyl ethyl sulfone(99485-10-6)
• EPA Substance Registry System: 1-phenylthio-2-chloroethyl ethyl sulfone(99485-10-6)

Safety Data

• Hazardous Substances Data: 99485-10-6(Hazardous Substances Data)

Upstream product

• 1889-59-4 ethyl vinyl sulfone 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 99485-28-6 1-phenylthiovinyl ethyl sulfone 

Relevant articles and documents

CAPTODATIVE SUBSTITUENT EFFECTS XXI. SYNTHESIS OF SELENENYLATED CAPTODATIVE OLEFINS VIA SELENENYL HALIDE ADDITION TO OLEFINS BEARING ELECTRON-WITHDRAWING SUBSTITUENTS

Addition of methane- and benzeneselenenyl bromide or chloride and benzene sulfenyl chloride to carbon-carbon double bonds substituted by electron-withdrawing groups is achieved in solvents of different polarity.Two regioisomeric adducts 6 and 7 or 8 and 9 are generally formed, which can be interconverted by equilibration in refluxing acetonitrile.It is of mechanistic interest that the regioisomers may also derive from selenenyltrihalide adducts.In comparison to acrylic esters, the propiolic ester reacts more slowly, producing mainly the α-selenenyl adduct.Dehydrohalogenation of adducts provides a general and valuable method for the preparation of olefins carrying methyl or phenylselenyl groups in α-position to electron-withdrawing substituents.