995-88-0Relevant academic research and scientific papers
REACTIONS OF O-(ALKYLCHLOROFORMOIMINO)-TRICHLOROMETHYLPHOSPHORANES WITH S-NUCLEOPHILES
Lyashenko, Yu. E.,Sokolov, V. B.
, p. 153 - 162 (2007/10/02)
Interactions of O-(alkylchloroformoimino)trichloromethylphosphoranes with hydrogen sulfide and mercaptans are reported; interaction with 2-mercaptoethanol is discussed and activation of the chlorine at a sp2 hybridized carbon by means of the phosphorane fragment is demonstrated in the substitution reactions with S-nucleophiles; the method of P=S bond formation in chlorophosphoranes by means of the reaction with thioacetic acid is suggested; some derivatives of O-alkylchloroformooximes are described. Key words: O-(alkylchloroformoimino)trichloromethylphosphoranes; O-(alkylchloroformoimino)chloromethylthionophosphonates; O-(alkylchloroformoimino)-O-alkylmethylthionophosphonates; bis(O-methylchloroformoimino)methylphosphonate; O-chloromethylphosphonate; O-(methyl-S-acetylformoimino)chloromethylthionophosphonate.
