99564-62-2Relevant academic research and scientific papers
An efficient and general method for the heck and buchwald-hartwig coupling reactions of aryl chlorides
Lee, Dong-Hwan,Taher, Abu,Hossain, Shahin,Jin, Myung-Jong
supporting information; experimental part, p. 5540 - 5543 (2011/12/15)
The β-diketiminatophosphane Pd complex acted as a powerful catalyst for the Heck coupling of aryl chlorides with alkenes. Various aryl and heteroaryl chlorides were coupled efficiently under relatively mild conditions. Furthermore, this catalytic system also proved to be highly active in the Buchwald-Hartwig coupling of deactivated and sterically hindered aryl chlorides at room temperature.
Base-free mizoroki-heck reaction catalyzed by rhodium complexes
Martinez, Remi,Voica, Florina,Genet, Jean-Pierre,Darses, Sylvain
, p. 3213 - 3216 (2008/02/11)
A base-free rhodium-catalyzed Mizoroki-Heck (M-H) reaction using potassium aryltrifluoroborates as the arylating agent of alkenes and acetone as a green "oxidant" is described. Thanks to the ready availability of organoboranes, this reaction should consti
