99566-38-8Relevant academic research and scientific papers
Facile, asymmetric addition of acetylene to aldehydes: In situ generation of reactive zinc acetylide
Sasaki, Hiroshi,Boyall, Dean,Carreira, Erick M.
, p. 964 - 971 (2007/10/03)
This study documents a process in which acetylene is employed directly in nucleophilic additions to aldehydes to give adducts in high levels of enantiomeric induction, up to 98% ee. To the best of our knowledge, this represents the first time in which acetylene itself has been utilized in such ligand-controlled enantioselective additions.
Absolute Structure and Activity Relationships of Cinnamyl Alcohol Derivatives of Pyrethroid Insecticides
Matsuo, Noritada,Yano, Toshihiko,Ohno, Nobuo
, p. 3029 - 3036 (2007/10/02)
Synthesis of three optically active pyrethroids containing cinnamyl-type alcohol moieties, and their insecticidal activity are reported.The presence of a m-phenoxy group at a benzene ring inverted the structure-activity relationships dramatically with respect to the absolute configuration of alcohol moieties.
