99597-99-6

Basic information

• Product Name: meta-chloromethylbenzoyloxy-3α cholanate de methyle
• Synonyms: meta-chloromethylbenzoyloxy-3α cholanate de methyle
• CAS NO: 99597-99-6
• Molecular Weight: 543.187
• Mol File: 99597-99-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: meta-chloromethylbenzoyloxy-3α cholanate de methyle(CAS DataBase Reference)
• NIST Chemistry Reference: meta-chloromethylbenzoyloxy-3α cholanate de methyle(99597-99-6)
• EPA Substance Registry System: meta-chloromethylbenzoyloxy-3α cholanate de methyle(99597-99-6)

Safety Data

• Hazardous Substances Data: 99597-99-6(Hazardous Substances Data)

Upstream product

• 63024-77-1 3-(Chloromethyl)benzoyl chloride 
• 1249-75-8 methyl lithocholate 

Relevant articles and documents

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A new backbone rearrangement is observed in A/B cis methyl lithocholate derivatives. It is initiated from the C-3 carbon either by dehalogenation of the chloroesters 1 by AgSbFg6 or by the action of the triflic anhydride on the si1y1ated ether 2. This rearrangement leads to methyl diacholenate 3 and new lactones in D-homoandrostane series 5 and 6. The differences of behaviour between A/B cis and A/B trans series and the mechanism of rearrangements are discussed.