99646-26-1Relevant academic research and scientific papers
Reactivite des liaisons ? uranium-carbone: reactions du methyltris(hexamethyldisilylamido)uranium
Dormond, A.,Aaliti, A.,Elbouadili, A.,Moise, C.
, p. 187 - 200 (2007/10/02)
The uranium-carbon ? bond of the methyltris(hexamethyldisilylamido)uranium, 3UCH3, was poorly reactive towards carbon monoxide insertion, but reacted readily with isocyanides, aliphatic nitriles and carbonyl compounds (aldehydes and ketones). "
Reactivity of the Actinoid-Carbon ? Bond: Reaction of 2MCH2Si(Me)2NSiMe3 with Acidic Hydrogen, Ready C-H Activation
Dormond, Alain,Bouadili, Abdel Aziz El,Moise, Claude
, p. 914 - 916 (2007/10/02)
The metal-carbon bond of the four-membered metallacycles 2MCH2Si(Me)2NSiMe3 (M = U, Th) reacts under mild conditions with acidic hydrogens of alcohols, phenols, and alkynes, with pyridine to give the orthometallated
