99656-33-4

Upstream product

• 141-97-9 ethyl acetoacetate 
• 88354-73-8 6-Phenylsulfanyl-cyclohex-2-enone 

Downstream Products

• 99656-30-1 (1S,5R,6R,12R)-5-Methoxy-12-phenylsulfanyl-3-trimethylsilanyloxy-tricyclo[7.3.1.0^1,6]tridec-3-en-7-one 
• 99656-31-2 Acetic acid (1R,5S,6S,12S)-7-oxo-12-phenylsulfanyl-tricyclo[7.3.1.0^1,6]tridec-3-en-5-yl ester 
• 113109-15-2 (1S,6S,12R)-5-Methyl-12-phenylsulfanyl-3-trimethylsilanyloxy-tricyclo[7.3.1.0^1,6]tridec-3-en-7-one 
• 99656-27-6 C₂₆H₃₆O₂SSi 
• 113109-18-5 (E)-4-((1R,2S)-7-Oxo-2-phenylsulfanyl-bicyclo[3.3.1]non-1-yl)-but-2-enoic acid methyl ester 
• 113109-16-3 (1R,5S,6R,12S)-5-Methyl-5-(4-methyl-pent-3-enyl)-12-phenylsulfanyl-3-trimethylsilanyloxy-tricyclo[7.3.1.0^1,6]tridec-3-en-7-one 
• 99656-29-8 (1R,6R,12S)-12-Phenylsulfanyl-tricyclo[7.3.1.0^1,6]tridec-3-en-7-one 
• 99656-25-4 (5R,8S)-8-Phenylsulfanyl-bicyclo[3.3.1]non-1-en-3-one 
• 113109-17-4 (1R,5S,6R,12S)-5-[2-(3,3-Dimethyl-oxiranyl)-ethyl]-5-methyl-12-phenylsulfanyl-3-trimethylsilanyloxy-tricyclo[7.3.1.0^1,6]tridec-3-en-7-one 

Relevant academic research and scientific papers

Cycloaddition Reactions of Bridgehead Enones

The cycloaddition reactions of bridgehead enones derived in situ from ketones 8,9, and 10 with various dienes at 0 deg C afford good yields of adducts.Even 1,1,3-trisubstituted dienes work well.The exclusive exo stereochemistry can be rationalized in term