99661-95-7Relevant academic research and scientific papers
STEROID GLYCOSIDES OF THE ROOTS OF Capsicum annuum. II. THE STRUCTURE OF THE CAPSICOSIDES
Gutsu, E. V.,Kintya, P. K.,Lazur'evskii, G. V.
, p. 202 - 205 (1987)
Two tigogenin glycosides and two diosgenin glycosides have been isolated from a methanolic extract of the roots of bush red pepper.An aattempt to isolate the individual spirostanol glycosides directly was unsuccessful.These compounds have very similar structures.For their separation, acetylation and epoxidation of the double bond of the aglycon, diosgenin, in the corresponding glycosides was performed.The derivatives obtained were purified by chromatography.To establish the complete chemical structure of each capsicoside we used both chemical and physical methods:complete and partial acid hydrolysis, methylation followed by methanolysis, IR spectroscopy, mass spectroscopy, etc.It was shown that capsicoside A2 is (25R)-5α-spirostan-3β-ol 3-O-β-D-galactopyranoside, capsicoside B2 is (25R)-5α-spirostan-3β-ol 3-O-4)-β-D-galactopyranoside>, capsicoside A3 is (25R)-spirost-5-en-3β-ol 3-O-β-D-galactopyranoside, and capsicoside B3 is identical with funkioside C.
