99664-59-2

Upstream product

• 15695-36-0 trans-{IrCl(N₂)(PPh₃)2} 
• 375-73-5 perfluorobutanesulfonic acid 

Downstream Products

• 110328-91-1 chlorohydridobis(bis(diphenylphosphino)ethane) nonafluorobutansulfonate 
• 99626-40-1 {((C₆H₅)3P)2(Cl)(H₂O)HIr(C₅H₂N₄(CH₃)(NH₂)(O))}⁽¹⁺⁾*C₄F₉SO₃^(1-) = {((C₆H₅)3P)2(Cl)(H₂O)(H)Ir(C₅H₂N₄(CH₃)(NH₂)(O))}SO₃C₄F₉ 
• 110352-98-2 chloro-hydrido-tris(triphenylphosphine)-iridium(III)-nonafluorobutanesulfonate 
• 99626-38-7 chloro-dinitrogen-hydrido-9-methylguanidine-bis-(triphenylphosphine)-iridium(III)-nonafluorobutansulfonate 

Relevant academic research and scientific papers

METALLORGANISCHE LEWIS-SAEUREN. XXIII. HYDRIDO-IRIDIUM(III)-KOMPLEXE MIT SCHWACH KOORDINIERTEN ANIONEN UND DISTICKSTOFF ALS ABGANGSGRUPPEN

The oxidative addition of HBF4 and C4F9SO3H to the nitrogen complex trans-(Ph3P)2Ir(N2)Cl gives the hydrido iridium(III) complexes (Ph3P)2(N2)(Cl)Ir(H)X (X-=FBF3-, OSO2C4F9-) in which the two excellent leaving groups(X- and N2) can be successively substituted by weak and strong donors (H2O, CH3OH, CH3COCH3, THF, CH3CN, CO, C2H4, PPh3; dithiocarbamate, valinate). (Ph3P)2(L)(Cl)Ir(H)FBF3 (L=CO, N2) catalyze the isomerization of 1,2-diphenyl- and phenyloxirane to diphenyl and phenyl acetaldehyde, respectively.