99668-81-2Relevant academic research and scientific papers
Allylation of 2-Alkanoyl 1,4-Quinones with Allylsilanes and Allylstannanes. Efficient Synthesis of Pyranonaphthoquinone Antibiotics
Uno, Hidemitsu
, p. 350 - 358 (2007/10/02)
Total syntheses of pyranonaphthoquinone antibiotics eleutherin, isoeleutherin, nanaomycin A, and deoxyfrenolicin are described.The crucial step in the route is a regioselective allylation of alkanoyl quinones with allylsilanes and allylstannanes.The allyl
LEWIS ACID MEDIATED ALLYLATION OF 2-ALKANOYL-1,4-QUINONES WITH ALLYLSILANE AND ALLYLSTANNANE
Naruta, Yoshinori,Uno, Hidemitsu,Maruyama, Kazuhiro
, p. 5221 - 5224 (2007/10/02)
Allyltrimethylstannane reacts with 2-alkanoyl-1,4-quinones regioselectively to afford conjugate addition products which can be derived to 2-alkanoyl-3-allylhydroquinone diacetate, while allyltriphenylsilane reacts with the quinone to give naphthofuran.
