99668-82-3

Upstream product

• 1125-55-9 2-Acetyl-1,4-benzoquinone 
• 3200-73-5 trans-2-butenyltrimethylstannane 
• 108-24-7 acetic anhydride 
• 81665-20-5 2-(1-methyl-2-propenyl)-3-acetylcyclohexa-3,5-dien-1-one-4-ol 

Relevant academic research and scientific papers

Allylation of 2-Alkanoyl 1,4-Quinones with Allylsilanes and Allylstannanes. Efficient Synthesis of Pyranonaphthoquinone Antibiotics

Total syntheses of pyranonaphthoquinone antibiotics eleutherin, isoeleutherin, nanaomycin A, and deoxyfrenolicin are described.The crucial step in the route is a regioselective allylation of alkanoyl quinones with allylsilanes and allylstannanes.The allyl

LEWIS ACID MEDIATED ALLYLATION OF 2-ALKANOYL-1,4-QUINONES WITH ALLYLSILANE AND ALLYLSTANNANE

Allyltrimethylstannane reacts with 2-alkanoyl-1,4-quinones regioselectively to afford conjugate addition products which can be derived to 2-alkanoyl-3-allylhydroquinone diacetate, while allyltriphenylsilane reacts with the quinone to give naphthofuran.