99758-22-2Relevant academic research and scientific papers
Gold catalysis: Non-spirocyclic intermediates in the conversion of furanynes by the formal insertion of an alkyne into an aryl-alkyl C-C single bond
Hashmi, A. Stephen K.,Haeffner, Tobias,Yang, Weibo,Pankajakshan, Sreekumar,Schaefer, Sascha,Schultes, Lara,Rominger, Frank,Frey, Wolfgang
supporting information, p. 10480 - 10486 (2012/11/07)
It takes al-kynes: The formation of furyl-substituted heterocycles from furanynes with donor groups on the furan-alkyne tether and mechanistic control experiments indicate the involvement of open-chained carbenium ions in the overall insertion of an alkyne into a C-C bond, rather than the usual spirocyclic intermediates (see scheme). Copyright
