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((C6H5)3P)2PtH(H2O)(1+)*HC(SO2CF3)2(1-)={((C6H5)3P)2PtH(H2O)}(HC(SO2CF3)2) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

99797-63-4

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99797-63-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 99797-63-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,9,7,9 and 7 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 99797-63:
(7*9)+(6*9)+(5*7)+(4*9)+(3*7)+(2*6)+(1*3)=224
224 % 10 = 4
So 99797-63-4 is a valid CAS Registry Number.

99797-63-4Downstream Products

99797-63-4Relevant academic research and scientific papers

Facile Addition and Elimination Reactions of Fluorocarbon Acids at Platinum

Siedle, A. R.,Newmark, R. A.,Gleason, W. B.

, p. 767 - 773 (2007/10/02)

Reaction of the fluorocarbon acid H2C(SO2CF3)2 with (Ph3P)2Pt(C2H4) yields trans-(Ph3P)2PtH in which restricted rotation about a covalent Pt-C bond was demonstrated by multinuclear NMR spectroscopy.This compound rearranges to the cis isomer by first-order kinetics and is rapidly solvolyzed by Lewis bases to afford trans-(Ph3P)2PtHL+-HC(SO2CF3)2- (L = CH3CN, DMF, CH3OH, H2O, and THF).Complexes containing weak Lewis bases (THF and CH3OH) are unstable and dimerize to form (Ph3P)3Pt2(μ-H)(μ-PPh2)Ph+HC(SO2CF3)2- , a = 14.039(2) Angstroem, b = 20.318(3) Angstroem, c = 13.626(3) Angstroem, α = 94.43(1) deg, β = 95.69(1) deg, γ = 77.47(1) deg, Z = 2, R = 0.059>.Solvolysis of the cis isomer is slower by a factor of ca. 18.

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