99834-22-7Relevant academic research and scientific papers
HIGHLY SELECTIVE FORMATION OF LINEAR-CONJUGATED DIENOLATE ANIONS FROM CONJUGATED ENONES
Kawanisi, Mituyosi,Itoh, Yasuko,Hieda, Takanori,Kozima, Sinpei,Hitomi, Torazo,Kobayashi, Kazuko
, p. 647 - 650 (1985)
Treatment of conjugated enones having both α'- and γ-hydrogens with KN(SiMe3)2 (KHMSA) in a mixed solvent of DMF with THF at -78 deg C afforded preferentially linear-conjugated dienolate anions, which were trapped by methyl chloroformate to give the corre
