99883-53-1

Upstream product

• 34638-25-0 (1R,5S)-2-oxabicyclo[3.3.0]oct-6-en-3-one 

Downstream Products

• 118215-77-3 5,8-dibenzyloxytricyclo(5.2.1.0^4,10)decan-2-one 
• 118535-94-7 C₃₁H₂₅Cl₃O₆ 
• 118535-95-8 C₂₄H₂₂Cl₂O₅ 
• 118215-76-2 (4aS,5R,6aS,6bR)-3,5-Bis-benzyloxy-4,4a,5,6,6a,6b-hexahydro-3H-cyclopenta[cd]pentalen-1-one 
• 118215-77-3 C₂₄H₂₆O₃ 
• 118215-72-8 C₂₃H₂₄O₂ 

Relevant academic research and scientific papers

SYNTHESIS AND CHIROPTICAL PROPERTIES OF C3-PERHYDROTRIQUINACENE DERIVATIVES

An efficient, enantioselective synthesis of C3-triketone 1, starting from optically pure lactone 2, which is commercially available in both enantiomeric forms, is described.The absolute configuration of a chiral perhydrotriquinacene derivative is therefore established for the first time by chemical correlation.The stereochemical assignments are also confirmed by the circular dichroism of both (+)-1, which shows a positive Cotton effect, and the tribenzoate (+)-12, which presents a positive exciton chirality.