99892-70-3

Upstream product

• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 106758-61-6 Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-[((E)-buta-1,3-dienyl)oxy]-tetrahydro-pyran-4-yl ester 
• 106758-59-2 (2E)-3-(2`,3`,4`,6`-tetra-O-acetyl-Β-D-glucopyranosyloxy)propenal 
• 106758-60-5 (1E)-(2',3',4',6'-tetra-O-acetyl-β-D-gucopyranosyloxy)buta-1,3-diene 
• 99892-66-7 3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyloxy)-1-propenal 
• 78-85-3 2-methylpropenal 
• 99892-69-0 (2R,3R,4S,5S,6R)-2-[((E)-Buta-1,3-dienyl)oxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol 
• 99892-67-8 but-1,3-dienyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 

Downstream Products

• 99892-72-5 (1R,2S)-2-Hydroxy-1-methyl-cyclohexanecarbaldehyde 
• 69551-50-4 (1S,2S)-2-Hydroxymethyl-2-methyl-cyclohexanol 
• 106680-70-0 (1R,2S)-1-Methyl-2-((2S,3S,4R,5R,6S)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexanecarbaldehyde 
• 99892-71-4 Acetic acid (2S,3S,4R,5S,6S)-4,5-diacetoxy-6-acetoxymethyl-2-((1S,6R)-6-formyl-6-methyl-cyclohex-2-enyloxy)-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Aqueous Cycloadditions Using Glyco-Organic Substrates. 1. Stereochemical Course of the Reaction

New water-soluble trans-butadienyl ethers were synthesized by using free glucose as the hydrophilic part.Aqueous cycloaddition with a variety of dienophiles showed rate and stereoselectivity enhancement in comparison with similar peracetylated dienes in o

GLYCO-ORGANIC SUBSTRATES IN ORGANIC SYNTHESIS. PREPARATION OF A WATER SOLUBLE BUTADIENYL-ETHER AND ITS USE IN AQUEOUS CYCLOADDITION.

A chiral water-soluble butadienyl-ether containing free glucose as hydrophilic moiety was synthesized and used in aqueous cycloaddition reaction with methacrolein to afford through pure endo transition state, only two diastereoisomers from which the sugar