99893-72-8

Basic information

• Product Name: pent-4-en-1-yl 3-chlorobenzoate
• Synonyms: pent-4-en-1-yl 3-chlorobenzoate
• CAS NO: 99893-72-8
• Molecular Weight: 224.687
• Mol File: 99893-72-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pent-4-en-1-yl 3-chlorobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: pent-4-en-1-yl 3-chlorobenzoate(99893-72-8)
• EPA Substance Registry System: pent-4-en-1-yl 3-chlorobenzoate(99893-72-8)

Safety Data

• Hazardous Substances Data: 99893-72-8(Hazardous Substances Data)

Upstream product

• 821-09-0 n-Pent-4-enyl alcohol 
• 535-80-8 3-chlorobenzoate 

Downstream Products

• 1454661-09-6 5-(diethoxyphosphoryl)-4-fluoropentyl 3-chlorobenzoate 

Relevant articles and documents

Silver-catalyzed radical phosphonofluorination of unactivated alkenes

We report herein a mild and catalytic phosphonofluorination of unactivated alkenes. With catalysis by AgNO3, the condensation of various unactivated alkenes with diethyl phosphite and Selectfluor reagent in CH 2Cl2/H2O/HOAc at 40 C led to the efficient synthesis of β-fluorinated alkylphosphonates with good stereoselectivity and wide functional group compatibility. A mechanism involving silver-catalyzed oxidative generation of phosphonyl radicals and silver-assisted fluorine atom transfer is proposed.