99894-22-1

Upstream product

• 99908-18-6 (1S,2R,4R)-1-[(Z)-2-(4-Chloro-benzenesulfonyl)-vinylsulfanylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol 
• 21286-54-4 Camphorsulfonyl chloride 
• 71242-58-5 (1S,2R,4R)-(-)-10-mercaptoisoboneol 

Downstream Products

• 99894-25-4 (1S,2R,4R)-1-[(R)-(1S,2R,3S,4R)-3-(4-Chloro-benzenesulfonyl)-bicyclo[2.2.1]hept-5-ene-2-sulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol 

Relevant academic research and scientific papers

Self-Induced Diastereoselective Oxidation of Vinyl Sulfides Bearing a Chiral Hydroxy Group as a Way of Preparation of Optically Active Sulfinyl Dienophiles and Their Use in the Asymmetric Diels-Alder Reaction to Cyclopentadiene

Dienophiles 4,5,4' and 5' add with excellent diastereoselectivity to cyclopentadiene as a result of the fact that they assembled most features that are known to govern facial selectivity.Their synthesis entails stereoselective Michael addition of hydroxyt

Asymmetric Diels-Alder Reactions of Sulphinyl-activated Dienophiles obtained via a Self-induced Chiral Oxidation

The Diels-Alder cycloaddition of activated vinyl sulphoxides (1), that are readily obtained by a self-induced chiral oxidation, proceeds highly diastereoselectively to form the corresponding cycloadducts (4) that can be converted into 2-substituted norbor