99897-04-8Relevant articles and documents
STEREOCONTROLLED SYNTHESIS OF TRICYCLO4,9>UNDECANE RING SYSTEM OF ACONITIUM ALKALOIDS
Ihara, Masataka,Ishida, Yohhei,Abe, Mariko,Toyota, Masahiro,Fukumoto, Keiichiro,Kametani, Tetsuji
, p. 1127 - 1130 (1985)
Intramolecular double Michael reaction of the α,β-unsaturated enone ester gave the tricyclo1,5>undecane derivative, which was stereoselectively converted into the tricyclo4,9>undecane derivative.
Stereocontrolled Synthesis of the CDF Part of Aconitum Alkaloids via Intramolecular Double Michael Reaction
Ihara, Masataka,Ishida, Yohhei,Abe, Mariko,Toyota, Masahiro,Fukumoto, Keiichiro,Kametani, Tetsuji
, p. 1155 - 1164 (2007/10/02)
Intramolecular double Michael reaction of the α,β-unsaturated enone ester (5) using lithium hexamethyldisilazide produced the tricyclo1,5>undecane derivative (4) in a highly stereoselective manner.The annulation of (5) was further inves