99898-35-8

Basic information

• Product Name: (2,6-diisopropylphenoxymethyl)nonamethylruthenocene
• CAS NO: 99898-35-8
• Molecular Weight: 547.787
• Mol File: 99898-35-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2,6-diisopropylphenoxymethyl)nonamethylruthenocene(CAS DataBase Reference)
• NIST Chemistry Reference: (2,6-diisopropylphenoxymethyl)nonamethylruthenocene(99898-35-8)
• EPA Substance Registry System: (2,6-diisopropylphenoxymethyl)nonamethylruthenocene(99898-35-8)

Safety Data

• Hazardous Substances Data: 99898-35-8(Hazardous Substances Data)

Upstream product

• 111143-98-7 η5-pentamethylcyclopentadienyl(1,2,3,4-tetramethylfulven)ruthenium tetrafluoroborate 
• 2078-54-8 2,6-diisopropylphenol 

Relevant articles and documents

PERMETHYLMETALLOCENE. V. REAKTIONEN DES DECAMETHYLRUTHENICENIUM-KATIONS

The novel decamethylruthenicenium cation + undergoes a facile deprotonation/oxidation reaction to yield a tetramethylfulvene cation *C5Me4-exo-CH2>+ (Cp*=η5-C5Me5), +, together with neutral 1.The reaction is promoted by weakly coordinating Lewis bases such as Cl-. + is also generated by hydride abstraction from 1 with Ph3CBF4.Addition of nucleophiles Nu to + gives neutral complexes RuCp*C5Me4CH2Nu (Nu=R2NH, ROH or OH-).The mechanism of formation of + is discussed with reference to electrochemically evaluated redox properties of the species involved.