99930-74-2Relevant academic research and scientific papers
Bismuth trichloride catalyzed efficient reductive etherification of carbonyl compounds with alcohols: A novel method for preparation of symmetrical and unsymmetrical ethers
Wada, Makoto,Nagayama, Sonoe,Mizutani, Kaori,Hiroi, Ryoichi,Miyoshi, Norikazu
, p. 248 - 249 (2007/10/03)
The reductive homocoupling of a carbonyl compound and heterocoupling of a carbonyl compound with a non-protected alcohol were both effected smoothly at room temperature with triethylsilane in the presence of a catalytic amount of bismuth trichloride to afford the corresponding ethers in good yields.
A NOVEL METHOD FOR THE PREPARATION OF SYMMETRICAL AND UNSYMMETRICAL ETHERS. TRITYL PERCHLORATE PROMOTED REDUCTION OF CARBONYL COMPOUNDS WITH TRIETHYLSILANE
Kato, Jun-ichi,Iwasawa, Nobuharu,Mukaiyama, Teruaki
, p. 743 - 746 (2007/10/02)
In the presence of a catalytic amount of trityl perchlorate, symmetrical ethers are prepared from aldehydes and triethylsilane, and unsymmetrical ethers are also obtained from carbonyl compounds, alkoxytrimethylsilanes and triethylsilane, in good yields, respectively.
