99930-87-7

Upstream product

• 99930-81-1 1-heptynyl p-tolyl (+)-(S)-sulfoxide 
• 1517-82-4 (1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate 
• 628-71-7 1-Heptyne 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 61307-38-8 1-heptynylmagnesium bromide 
• 66-25-1 hexanal 

Downstream Products

• 117917-61-0 (+)-(R_CR_S)-2-(dimethylphenylsilyl)heptyl p-tolyl sulfoxide 
• 117917-60-9 (+)-(S_CR_S)-2-(dimethylphenylsilyl)heptyl p-tolyl sulfoxide 
• 122833-96-9 1-Methyl-4-((R)-(1S,2S)-4-methylene-2-pentyl-cyclopentanesulfinyl)-benzene 
• 122920-82-5 1-Methyl-4-((R)-(1R,2R)-4-methylene-2-pentyl-cyclopentanesulfinyl)-benzene 
• 1242174-79-3 C₂₃H₃₀O₂S 
• 1242174-80-6 C₂₈H₃₂O₂S 
• 1242174-78-2 C₂₁H₂₆O₂S 
• 123975-90-6 trans-4-pentyl-5-p-tolylthio-4,5-dihydrofuran-2(3H)-one 
• 123976-07-8 (4S,5R)-4-pentyl-5-p-tolylsulphonyl-4,5-dihydrofuran-2(3H)-one 
• 117917-74-5 (-)-(S)-2-(dimethylphenylsilyl)heptyl-p-tolyl sulfone 
• 117917-73-4 (+)-(R)-2-(dimethylphenylsilyl)heptyl p-tolyl sulfone 
• 103981-11-9 (-)-(S)-2-(dimethylphenylsilyl)heptane 
• 123975-89-3 trans-3,3-dichloro-4-pentyl-5-p-tolylthio-4,5-dihydrofuran-2(3H)-one 

Relevant academic research and scientific papers

ASYMMETRIC INDUCTION IN THE PALLADIUM CATALYZED CYCLOADDITION REACTION OF TRIMETHYLENEMETHANE WITH HOMOCHIRAL VINYLSULFOXIDES

The palladium catalyzed cycloaddition of trimethylenemethane with a variety of vinylsulfoxides led to cycloadducts in good to excellent chemical yields and with a good level of asymmetric induction.

Simple and Stereocontrolled Preparation of Optically Pure (E)- and (Z)-1-Alkenyl p-Tolyl Sulfoxides via 1-Alkynyl p-Tolyl Sulfoxides

1-Alkynylmagnesium bromides react cleanly and stereospecifically with (-)-menthyl (-)-(S)-p-toluenesulfinate (2) in toluene to produce chiral 1-alkynyl p-tolyl (+)-(S)-sulfoxides 5a-d in high yields.Reduction of 5a-d with lithium aluminum hydride in THF a

A SIMPLE PREPARATIVE METHOD FOR OPTICALLY PURE 1-ALKENYL p-TOLYL SULFOXIDES VIA 1-ALKYNYL p-TOLYL SULFOXIDES

1-Alkynyl Grignard reagents react with (SS)-(-)-menthyl p-toluene-sulfinate in toluene to give optically active 1-alkynyl p-tolyl sulfoxides in high yields.The 1-alkynyl sulfoxides thus obtained undergo a stereoselective hydroalumination follow