99935-48-5

Upstream product

• 18925-10-5 allylzinc bromide 
• 100018-34-6 n-butyl N-((1S)-phenylethyl)-α-iminoacetate 
• 53317-08-1 allyl-9-borabicyclo<3.3.1>nonane 
• 67321-50-0 C₁₄H₁₉NO₂ 
• 24850-33-7 allyltributylstanane 
• 6295-06-3 butyl glyoxalate 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 53317-08-1 9-allyl-9-bora-bicyclo[3.3.1]nonane 

Relevant academic research and scientific papers

Remote stereocontrol in reactions between 4- and 5-alkoxyalk-2- enylstannanes and 1-alkoxycarbonylimines and analogues: Stereoselective approaches to novel α-amino acids

Reactions of the allyltin trichloride 45 generated from (4S)-4-benzyloxypent-2-enyl(tributyl)stannane 1 with imines prepared from glyoxylates proceed with useful levels of 1,5-stereocontrol in favour of (4E)-2,6-anti-2-(alkylamino)-6-benzyloxyhept-4-enoat

Very High 1,2- and 1,3-Asymmetric Induction in the Reactions of Allylic Boron Compounds with Chiral Imines

The reaction of allyl-9-borabicyclononane (allyl-9-BBN) with chiral imines 3 produced the Cram isomer 4 either exclusively or very predominantly.The very high 1,2-asymmetric induction is explained by a six-membered chairlike transition state, in wh

Enantio- and Diastereo-selective Synthesis of Amino Acids via the Reaction of Allylic Boron Compounds with α-Imino-esters

Very high enantio- and diastereo-selective syntheses of certain amino acids may be realized through the reaction of 9-allyl- and 9-but-2-enyl-9-borabicyclononane with α-imino-esters.