ISOFRAX? 1260C BOARD LD DATE OF FIRST ISSUE: 01/02/2002
MSDS NUMBER: M0370
MATERIAL SAFETY DATA SHEET
1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY
IDENTIFICATION OF THE PRODUCT
ISOFRAX? THERMAL INSULATION PRODUCTS contain alkaline-earth-silicate fibers (magnesium
silicate)
IDENTIFICATION OF THE COMPANY
Unifrax Corporation
2351 Whirlpool St.
Niagara Falls, NY 14305-2413
Product Stewardship Information Line
1-800-322-2293 (Monday - Friday 8:00 a.m. - 4:30 p.m. EST)
CHEMTREC Emergency Assistance: 1-800-424-9300
2. COMPOSITION / INFORMATION ON INGREDIENTS
DESCRIPTION
White, odorless board.
COMPOSITION
CAS Number % by Weight
Amorphous magnesium silicate (alkaline-earth-silicate) MIXTURE 80-90
(SiO2 70-80 %, MgO 18-27 %, trace elements 0-4 %)
Silica (amorphous) 7631-86-9 10-15
Starch 56780-58-6 3-7
3. HAZARDS IDENTIFICATION
MAY IRRITATE EYES, SKIN and RESPIRATORY TRACT
May cause temporary mechanical irritation to eyes, skin, and respiratory tract (nose,
throat & lungs).
Pre-existing medical conditions, including dermatitis, asthma or chronic lung disease
may be aggravated by exposure; individuals who are atopic (with a history of
allergies) may experience greater amounts of skin and respiratory irritation.
4. FIRST AID MEASURES
FIRST AID PROCEDURES
EYE IRRITATION
If eyes become irritated, wash immediately with large amounts of lukewarm water for at
least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough
rinsing. Do not rub eyes. Get medical attention if irritation persists.
SKIN IRRITATION
If skin becomes irritated, do not rub or scratch exposed skin. Wash area of contact
thoroughly with soap and water. Using a skin cream or lotion after washing may be
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ISOFRAX? 1260C BOARD LD MSDS No. M0370
helpful. Change into clean clothing.
RESPIRATORY TRACT IRRITATION
If respiratory tract (nose, throat, lungs) irritation occurs, relocate individual to a
dust free environment. Get medical attention, if irritation continues. See Section 8
for additional measures to reduce or eliminate exposure.
5. FIRE FIGHTING MEASURES
Non-combustible (does not burn) product.
Packaging and surrounding materials may be combustible.
Use extinguishing agent suitable for surrounding combustible materials.
6. ACCIDENTAL RELEASE MEASURES
SPILL PROCEDURES
Provide workers with respirators, if needed. [See Section 8]
Limit airborne dust dispersion by wetting the materials with water.
CLEAN UP
Use high efficiency vacuum to clean up spilled material. Use wet sweeping or a dust
suppressant where sweeping is necessary. Do not use compressed air for clean up.
ENVIRONMENTAL PROTECTION
Clean up spilled material to the extent possible. Package spilled material properly
for disposal. Do not allow to be wind blown. Do not flush spilled material into
drains. Prevent spilled materials from entering natural water courses. Check with
your employer to identify all regulations which may apply.
7. HANDLING AND STORAGE
HANDLING AND STORAGE
Minimize airborne dusts by avoiding the unnecessary disturbance of materials.
CLEAN-UP
Clean up dust carefully. Use wet sweeping or high efficiency vacuum to remove dust.
Do not use compressed air.
During after-service removal activities, wet exposed material frequently to minimize
airborne dust. A surfactant may be added to the water to improve the wetting process.
Use only enough water to wet the insulation. Do not allow water to accumulate on
floors. [See Section 16 - After-Service Removal]
EMPTY CONTAINERS
Product packaging may contain residue. Do not reuse.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
INDUSTRIAL HYGIENE STANDARDS AND OCCUPATIONAL EXPOSURE LIMITS
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ISOFRAX? 1260C BOARD LD MSDS No. M0370
Components OSHA SUPPLIE
Magnesium silicate fiber None established* See below**
Silica (amorphous) 6 mg/m3 (< 1% None Established
crystalline silica)
Starch 5 mg/m3 PEL (resp. None Established
dust)
15 mg/m3 PEL (total
dust)
ACGIH TLV'S: Magnesium silicate fiber -- None established. Silica (amorphous) -- 10
mg/m3 (total Dust, containing < 1% crystalline silica), 3 mg/m3 (respirable dust,
containing < 1% crystalline silica). Starch -- 10 mg/m3 TLV (total dust)
*For magnesium silicate fiber, refer to OSHA guidance regarding "Particulates Not
Otherwise Regulated" (PNOR). Control airborne dust levels as follows:
Components Particle Size OSHA
PNOR Total Dust 15 mg/m3
Respirable Dust 5 mg/m3
ACGIH Particulates Not Otherwise Classified (PNOC) -- Inhalable particulate: 10 mg/m3.
Respirable particulate: 3 mg/m3.
** As with most industrial materials, it is prudent to minimize unnecessary exposure
to respirable dusts. Note that Industrial hygiene standards and occupational exposure
limits differ between countries and local jurisdictions. Check with your employer to
identify any "respirable dust", "total dust" or "fiber" exposure standards to follow
in your area. If no regulatory dust or fiber control standard apply, a qualified
industrial hygiene professional can assist with a specific evaluation of workplace
conditions and the identification of appropriate respiratory protection practices. In
the absence of other guidance, the supplier has found that it is generally feasible to
control occupational fiber exposure to 1 f/cc or less.
ENGINEERING CONTROLS:
Dust suppressing control technologies such as local exhaust ventilation, point of
generation dust collection, down draft work stations, emission controlling tool
designs, and materials handling equipment are effective means of minimizing airborne
fiber emissions. For additional information, contact the Unifrax Corporation Product
Stewardship Information Line at 1-800-322-2293 (See Section 16).
PERSONAL PROTECTION EQUIPMENT
Eye Protection:
In case of overhead work, wear goggles or safety glasses with side shields to prevent
eye contact.
Skin Protection:
Wear gloves, head coverings and full body clothing as necessary to prevent skin
irritation.
Respiratory Protection:
When effective engineering and/or administrative controls are insufficient, the use of
appropriate respiratory protection, pursuant to the requirements of OSHA 1910.134, is
recommended. For dust concentrations below applicable exposure limit value, PPE is
not required. The evaluation of workplace hazards and the identification of
appropriate respiratory protection is best performed on a case by case basis, by a
qualified Industrial Hygienist.
9. PHYSICAL AND CHEMICAL PROPERTIES
Oxidizing properties None
Odor None
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ISOFRAX? 1260C BOARD LD MSDS No. M0370
Melting point 1500-1550??C (2730-2820??F)
Flammability None
Explosive properties None
10. STABILITY AND REACTIVITY
CONDITIONS OR MATERIALS TO AVOI
Avoid direct contact with strong acid environments.
11. TOXICOLOGICAL INFORMATION
EPIDEMIOLOGY
This product has not been the subject of epidemiological study. Epidemiological
studies related to other fiber chemistries of similar solubility have not identified a
statistically significant incidence of exposure-related respiratory disease.
TOXICOLOGY
This product has been the subject of limited testing.
A review of available scientific literature suggests an inverse relationship between
dissolution rate and potential health effects; i.e. the higher the dissolution rate of
a fiber the lower its potential to produce health effects. The dissolution rate of
Isofrax? fiber has been determined through standardized in vitro testing. The
dissolution rate of Isofrax? fibers is higher than that of other fiber types that have
been tested in chronic animal studies and did not produce respiratory disease.
This product possesses a fiber chemistry within the regulatory (European Commission
Directive 97/69/EC) definition as a "man-made vitreous (silicate) fiber with random
orientation with alkaline oxide and alkaline earth oxide (Na2O + K2O + CaO + MgO +
BaO) content greater than 18% by weight". Isofrax? fibers have been tested pursuant
to EU protocol ECB/TM/26, rev. 7, Nota Q, Directive 97/69/EC. The results for the
short term biopersistence test by inhalation (IH test) was 6 days; well below the
regulatory threshold of 10 days cited in Directive 97/69/EC. Based on testing
results, Isofrax? based products are not regarded as potential carcinogens and they
ARE EXEMPT from European classification as such. By virtue of these test results,
these products ARE EXEMPT from European regulatory guidelines that require hazard
warning labels with specific risk phrases citing respiratory disease potential. In
addition, Isofrax fibers have been tested in an independent laboratory, by
intratracheal (IT test) instillation, under a protocol that was consistent with the
requirements of the German Hazardous Substances Ordinance (BGBI. I pp. 1782, 2049,
Third Amendment, Appendix V, No. 7). The half-life clearance of Isofrax? fibers was
32.7 days; well below the applicable regulatory thresholds. Based on the IT test
results, Isofrax products ARE EXEMPT from the requirements of the German Ordinance.
The definition of "irritant" contained in the hazard communication standard, 29 CF 1900.1200, Appendix A, is "...a reversible inflammatory effect on living tissue by
chemical action...". Isofrax? fiber is an inert material which doesn't interact
chemically with exposed skin. However, there is a possibility that exposure to this
product may cause temporary mechanical irritation to the eyes, skin or respiratory
tract (nose, throat, lungs). This temporary irritation can be mitigated with proper
handling practices designed to limit exposure and the use of protective clothing
(glasses, gloves, clothing).
This product has not been specifically evaluated by any regulatory authority or other
classification entity, such as the International Agency for Research on Cancer (IARC)
or the National Toxicology Program (NTP). Other types of man-made vitreous fibers
(MMVF) have been evaluated and subsequently classified as potential carcinogens.
Various classifications, such as "possible carcinogen", "probable carcinogen", and
"reasonably anticipated to be a carcinogen" have been given to other MMVF's.
12. ECOLOGICAL INFORMATION
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ISOFRAX? 1260C BOARD LD MSDS No. M0370
No ecological concerns have been identified.
13. DISPOSAL CONSIDERATIONS
As produced, this product is usually accepted for disposal at most sites licensed for
the disposal of industrial waste. Check applicable regulations and waste site
policies prior to disposal. Waste should be placed in sealed containers for disposal.
In case of contamination, by other materials classified as hazardous waste, expert
guidance should be sought.
14. TRANSPORT INFORMATION
Product should remain in sealed containers during transportation.
15. REGULATORY INFORMATION
Key statutory and regulatory classification or listings for the product, as
manufactured, which may impact product storage, use, handling or disposal:
U.S. FEDERAL REGULATIONS
SARA TITLE III: This product is not regulated under SARA Sections 302, 304, 311/312
and 313.
Comprehensive Environmental Response
Compensation and Liability Act of 1980 (CERCLA):
ISOFRAX? THERMAL INSULATION fibers are composed of fiber with an average diameter
greater than 1 micron, and therefore are not considered CERCLA hazardous
substances. See 60 FR 30934 (June 12, 1995).
Clean Air Act (CAA):
ISOFRAX? THERMAL INSULATION fibers are composed of fiber with an average diameter
greater than 1 micron, and therefore are not considered hazardous air pollutants.
See 60 FR 30934 (June 12, 1995).
Toxic Substances Control Act (TSCA):
All substances in this product are listed, as required, on the TSCA inventory.
STATE REGULATIONS
California: Magnesium silicate fiber has not been listed by the State of California
on Proposition 65, the Safe Drinking Water and Toxic Enforcement Act of
1986.
New Jersey: Magnesium silicate fiber is not listed as a special health hazard
substance as defined in New Jersey Worker and Community Right to Know
Act, New Jersey Administrative Code, Title 8, Department of Health,
Chapter 59, Subchapter 10.
Pennsylvania: Magnesium silicate fiber is not listed as a special health hazard
substance as defined in Pennsylvania Right-to-Know Law, Section 3800.
INTERNATIONAL REGULATIONS
Canadian Workplace Hazardous Materials Information System (WHMIS):
No Canadian Workplace Hazardous Materials Information System (WHMIS) categories apply
to this product.
Canadian Environmental Protection Act (CEPA):
All substances in this product are listed, as required, on the Domestic Substances
List (DSL).
No chemicals in this product are listed on the Non-Domestic Substances List.
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ISOFRAX? 1260C BOARD LD MSDS No. M0370
European Directive 97/69/EC
By virtue of testing results, Isofrax? fiber has been exempted from classification
and labeling as a potential carcinogen.
German Hazardous Substances Ordinance
By virtue of testing results, Isofrax? fiber may be used without the limitations or
concern for requirements imposed on other man-made mineral fibers by the Ordinance.
16. OTHER INFORMATION
After-Service Isofrax? Thermal Insulation: Removal
As produced, Isofrax fibers are vitreous (glassy) materials which do not
contain crystalline silica. Continued exposure to elevated temperatures can
cause the vitreous magnesium-silicate (alkaline-earth-silicate) fibers to
devitrify (become crystalline). Clinoenstatite is the first crystalline
formation to occur at approximately 1472?? F. (800?? C). Clinoenstatite
formation peaks at approximately 1832?? F. (1000?? C), after which
Protoenstatite (compositionally the same as Clinoenstatite) begins to form.
Crystalline phase silica (Cristobalite) formation is possible at
temperatures of approximately 2192?? F. (1200?? C), however, the formation of
crystalline silica is highly dependent on temperature, the duration of time
that the fibers are exposured to high temperatures, fiber chemistry and/or
the presence of fluxing agents. The formation of crystalline silica can
only be confirmed through laboratory analysis of the "hot face" fiber.
IARC??s evaluation of crystalline silica states "Crystalline silica inhaled in the form
of quartz or cristobalite from occupational sources is carcinogenic to humans (Group
1)" and additionally notes "carcinogenicity in humans was not detected in all
industrial circumstances studied" (IARC Monograph Vol. 68, 1997). NTP lists all
polymorphs of crystalline silica amongst substances which may "reasonably be
anticipated to be carcinogens".
During removal operations, the use of a full face respirator is recommended to reduce
inhalation exposure along with eye & respiratory tract irritation. A specific
evaluation of workplace hazards and the identification of appropriate respiratory
protection is best performed, on a case by case basis, by a qualified industrial
hygiene professional. For more detailed information regarding respirable crystalline
silica, call the Product Stewardship Information Hotline (see below).
Product Stewardship Program
The Unifrax Corporation has established a program to provide customers with up-to-date
information regarding the proper use and handling of fiber-based products, including
ISOFRAX? THERMAL INSULATION. In addition, Unifrax Corporation has also established a
program to monitor airborne fiber concentrations at customer facilities. If you would
like more information about this program, please call the Unifrax Corporation Product
Stewardship Information Line at 1-800-322-2293.
Revision Summary: Sections 2 and 16 updated. Trademark updated. Replaces 02/23/2000
MSDS.
MSDS Prepared By: UNIFRAX RISK MANAGEMENT DEPARTMENT
DISCLAIME The information presented herein is based on data considered to be accurate as of the date of
preparation of this Material Safety Data Sheet. However, no warranty or representation, express
or implied, is made as to the accuracy or completeness of the foregoing data and safety
information. In addition, no responsibility can be assumed by vendor for any damage or injury
resulting from abnormal use, from any failure to adhere to recommended practices, or from any
hazards inherent in the nature of the product.
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More Unifrax High Temperature Insulation Information On The Web:
http://www.unifrax.com
Official Unifrax High Temperature Insulation Website
http://www.high-temperature-insulation.com
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http://www.refractory-ceramic-fiber.com
Unifrax Refractory Ceramic Fiber Information
Official Fiberfrax Refractory Ceramic Fiber High
http://www.fiberfrax.com
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Official Foamfrax Advanced High Temperature
http://www.foamfrax.com
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Official Insulfrax Soluble Fiber High Temperature
http://www.insulfrax.com
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http://www.isofrax.com
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http://www.fyrewrap.com
Official Fyrewrap Fire Prevention Products Information
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