The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.

DuPont Material Safety Data Sheet

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"ZONYL" BA Fluorotelomer Intermediate
5962PP Revised 6-DEC-2007
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CHEMICAL PRODUCT/COMPANY IDENTIFICATION
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Material Identification

"ZONYL" is a registered trademark of DuPont.

Corporate MSDS Number : DU002423

Company Identification

MANUFACTURER/DISTRIBUTO DuPont
1007 Market Street
Wilmington, DE 19898

PHONE NUMBERS
Product Information : 1-800-441-7515 (outside the U.S.
302-774-1000)
Transport Emergency : CHEMTREC 1-800-424-9300(outside U.S.
703-527-3887)
Medical Emergency : 1-800-441-3637 (outside the U.S.
302-774-1000)

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COMPOSITION/INFORMATION ON INGREDIENTS
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Components

Material CAS Number %
1,1,2,2-Tetrahydroperfluoro-1-Hexanol 2043-47-2 1-2
1,1,2,2-Tetrahydroperfluoro-1-Octanol 647-42-7 27-34
1,1,2,2-Tetrahydroperfluoro-1-Decanol 678-39-7 29-34

865-86-1
1,1,2,2-Tetrahydroperfluoro-1-Dodecanol 17-21

39239-77-5
1,1,2,2-Tetrahydroperfluoro-1-Tetradecanol 6-9

60699-51-6
1,1,2,2-Tetrahydroperfluoro-1-Hexadecanol 2-5

65104-67-8
1,1,2,2-Tetrahydroperfluoro-1-Octadecanol 1-2
5962PP DuPont Material Safety Data Sheet

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HAZARDS IDENTIFICATION
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Potential Health Effects

Skin contact may cause skin irritation with discomfort or
rash. Data to evaluate the skin permeation hazard of this
compound are insufficient. There are no reports of human
sensitization.

Eye contact may cause eye irritation with discomfort,
tearing, or blurring of vision.

Based on animal experiments, gross overexposure may cause
abnormal liver or kidney function as detected by laboratory
tests.


Based on related products, inhalation of spray or mist may cause
nasal, throat, or lung irritation. Inhalation of large amounts of
respirable particles may be toxic to the lungs. Symptoms may be
modest initially, followed in hours by severe shortness of breath
requiring prompt medical attention.

Carcinogenicity Information

None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.

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FIRST AID MEASURES
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First Aid

INHALATION

If inhaled, remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
Call a physician.

SKIN CONTACT

Flush skin with water after contact. Wash contaminated clothing
before reuse.

EYE CONTACT

In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.

INGESTION

If swallowed, do not induce vomiting. Immediately give 2 glasses
of water. Never give anything by mouth to an unconscious person.
Call a physician.
5962PP DuPont Material Safety Data Sheet

(FIRST AID MEASURES - Continued)

Notes to Physicians

Activated charcoal mixture may be administered. To prepare
activated charcoal mixture, suspend 50 grams activated charcoal in
400 mL water and mix thoroughly. Administer 5 mL/kg, or 350 mL
for an average adult.

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FIRE FIGHTING MEASURES
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Flammable Properties

Flash Point : Does not ignite
Method : PMCC

Noncombustible. Hazardous decomposition products including carbon
dioxide, carbon monoxide, hydrogen fluoride, toxic gases or
particles may be formed during combustion. These products may
cause severe eye, nose, throat, and lung irritation or toxic
effects.

Extinguishing Media

Water Spray, Foam, Dry Chemical, CO2.

Fire Fighting Instructions

Evacuate personnel to a safe area. Wear self-contained breathing
apparatus.

Avoid breathing decomposition products.

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ACCIDENTAL RELEASE MEASURES
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Safeguards (Personnel)

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Spill Clean Up

Shovel or sweep up.

Accidental Release Measures

Flush spill area with water.
5962PP DuPont Material Safety Data Sheet

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HANDLING AND STORAGE
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Handling (Personnel)

Avoid contact with eyes. Avoid contact with skin. Avoid contact
with clothing. Wash thoroughly after handling. Do not store or
consume food, drink, or tobacco in areas where they may become
contaminated with this material. Avoid circumstances that produce
respirable particles unless suitable ventilation and respirator
are used.

Handling (Physical Aspects)

For safely thawing the product, place drums in thaw room or
hot water bath, at temperature not above 75C. Contact
DuPont for additional assistance as needed. Do not use a
metal band heater on these drums, or use any other method
that exposes the drum to extreme temperatures of
metal-to-metal contact.

Storage

Keep container tightly closed.

Keep away from open flames and heated surfaces above 200
degrees C (392 deg F).

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EXPOSURE CONTROLS/PERSONAL PROTECTION
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Engineering Controls

Keep container tightly closed. Use only with adequate ventilation.
Vent heated extruder or dryer fumes outside work area. Do not
aerosolize. In spray applications, use airless type pressure
spray equipment at less than 60 psi, and exhaust ducts, drip pans,
or other design features to minimize worker exposure to mists and
overspray.

Keep away from open flames and heated surfaces above 200
degC (392 degF).

Personal Protective Equipment

EYE FACE PROTECTION

Wear safety glasses or coverall chemical splash goggles.

RESPIRATORS

Where there is potential for airborne exposures in excess of
applicable limits, wear NIOSH approved respiratory
protection.

PROTECTIVE CLOTHING
5962PP DuPont Material Safety Data Sheet

(EXPOSURE CONTROLS/PERSONAL PROTECTION - Continued)

Where there is potential for skin contact have available and
as appropriate, impervious gloves, apron, pants, and jacket.

Exposure Guidelines

Exposure Limits
"ZONYL" BA Fluorotelomer Intermediate
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 5 mg/m3, 8 Hr. TWA
15 mg/m3, 15 minute TWA

* AEL is DuPont??s Acceptable Exposure Limit. Where governmentally
imposed occupational exposure limits which are lower than the AEL
are in effect, such limits shall take precedence.

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PHYSICAL AND CHEMICAL PROPERTIES
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Physical Data

Boiling Point : 145-245 C (293-473 F) @ 760 mm Hg
Melting Point : 55-65 C (131-149 F)
Solubility in Water : Negligible
Odor : Wax-like
Form : Solid, Waxy
Color : Pale to Medium Tan
Specific Gravity : 1.7

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STABILITY AND REACTIVITY
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Chemical Stability

Stable at normal temperatures and storage conditions.

Incompatibility with Other Materials

None reasonably foreseeable.

Decomposition

Hazardous decomposition products including carbon dioxide, carbon
monoxide, hydrogen fluoride, toxic gases or particles may be
formed during combustion. These products may cause severe eye,
nose, throat, and lung irritation or toxic effects.

Polymerization

Polymerization will not occur.
 5962PP DuPont Material Safety Data Sheet

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TOXICOLOGICAL INFORMATION
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# Animal Data

Inhalation 4 hour LC50: 35.3 mg/l in rats
Oral ALD: 11,000 mg/kg in rats

The product is a slight skin irritant, a slight eye
irritant, and is not a skin sensitizer in animals. The
effects in animals exposed by inhalation to single high
doses include irregular breathing, salivation, and discharge
from the eyes and nose. Large repeated doses (approximately
1000 times the AEL) caused slight liver and kidney damage.
Repeated doses of approximately 20 mg/m3 had no effects. The
effects in animals exposed by ingestion to single high doses
include irregular respiration, weight loss, diarrhea and
weakness. Repeated exposure caused reversible liver and
kidney changes. The product was negative in the Bacterial
Reverse Mutation Test with an independent repeat assay. An
In Vitro mammalian chromosome aberration test using human
peripheral lymphocytes was negative.

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ECOLOGICAL INFORMATION
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Ecotoxicological Information

Aquatic Toxicity:

48 hour EC50 - Algae: >1000 mg/L
48 hour EC50 - Daphnia magna: 965 mg/L

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DISPOSAL CONSIDERATIONS
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Waste Disposal

Treatment, storage, transportation, and disposal must be in
accordance with applicable Federal, State/Provincial, and Local
regulations. Do not burn.

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TRANSPORTATION INFORMATION
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Shipping Information

Not Regulated as a hazardous material by DOT, IMO, or IATA.
5962PP DuPont Material Safety Data Sheet

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REGULATORY INFORMATION
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U.S. Federal Regulations

TSCA Inventory Status : Reported/Included.

TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312

Acute : Yes
Chronic : No
Fire : No
Reactivity : No
Pressure : No

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OTHER INFORMATION
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NFPA, NPCA-HMIS

NPCA-HMIS Rating
Health :2
Flammability :0
Reactivity :0

Personal Protection rating to be supplied by user depending on use
conditions.

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The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.

Responsibility for MSDS : MSDS Coordinator
Address : DuPont Chemical Solutions Enterprise
Wilmington, De. 19898
Telephone : 800-441-7515

# Indicates updated section.

This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.

End of MSDS


1H,1H,2H,2H-Perfluoro-1-decanol