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Position: Index > Categories > Semiconductors and Actives
CAS : 12033-82-8
1.
1.1
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifiers
Product name
Product Number
Brand
CAS-No.
:
:
:
:
Strontium nitride
756423
Anonymous
12033-82-8
1.2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
:
Laboratory chemicals, Manufacture of substances
2.
2.1
2.2
HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Skin irritation (Category 2)
Eye irritation (Category 2)
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Irritating to eyes, respiratory system and skin.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word
Hazard statement(s)
H315
H319
H335
Precautionary statement(s)
P261
P305 + P351 + P338
Warning
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Avoid breathing dust.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard information (EU)
EUH014
Reacts violently with water.
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R36/37/38
S-phrase(s)
S26
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
2.3
3.
3.1
Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula
Molecular Weight
Component
Strontium nitride, powder
:
:
Sr3N2
290,87 g/mol
Concentration
CAS-No.
EC-No.
Barium
CAS-No.
EC-No.
12033-82-8
234-795-2
7440-39-3
231-149-1
-
< 10 %
4.
4.1
4.2
4.3
5.
5.1
5.2
FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
Prolonged or repeated exposure may cause:, Damage to the lungs., Material is extremely destructive to
tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Symptoms of exposure may
include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting.
Indication of any immediate medical attention and special treatment needed
no data available
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Dry powder
Special hazards arising from the substance or mixture
no data available
5.3
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Do not flush with water. Keep
in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Never allow product to get in contact with water during storage.
Air and moisture sensitive. Handle and store under inert gas.
Specific end uses
no data available
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, Flame retardant protective clothing, The type of protective equipment must be
selected according to the concentration and amount of the dangerous substance at the specific
workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
9.
9.1
PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour Threshold
pH
Melting point/freezing
point
Initial boiling point and
boiling range
Flash point
Evaporation rate
Form: Powder and fragments
Colour: black
no data available
no data available
no data available
Melting point/range: 1.030 °C
no data available
no data available
no data available
i)
Flammability (solid, gas) no data available
j)
k)
l)
Upper/lower
flammability or
explosive limits
Vapour pressure
Vapour density
no data available
no data available
no data available
m) Relative density
no data available
n)
o)
p)
q)
r)
s)
t)
Water solubility
Partition coefficient: n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive properties
Oxidizing properties
no data available
no data available
no data available
no data available
no data available
no data available
no data available
9.2
10.
10.1
10.2
10.3
Other safety information
no data available
STABILITY AND REACTIVITY
Reactivity
Reacts violently with water.
Chemical stability
no data available
Possibility of hazardous reactions
Reacts violently with water.
10.4
10.5
10.6
11.
11.1
Conditions to avoid
Exposure to moisture.
Incompatible materials
Strong oxidizing agents, Water
Hazardous decomposition products
Other decomposition products - Ammonia
TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 2.750 mg/kg
LD50 Oral - mouse - 1.826 mg/kg
LD50 Intraperitoneal - rat - 540 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
May be harmful if inhaled. Causes respiratory tract irritation.
May be harmful if swallowed.
May be harmful if absorbed through skin. Causes skin irritation.
Causes serious eye irritation.
Signs and Symptoms of Exposure
Prolonged or repeated exposure may cause:, Damage to the lungs., Material is extremely destructive to
tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Symptoms of exposure may
include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting.
Additional Information
RTECS: Not available
12.
12.1
ECOLOGICAL INFORMATION
Toxicity
no data available
12.2
12.3
12.4
12.5
12.6
13.
13.1
14.
14.1
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available
DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION
UN number
14.2
ADR/RID: 2813
UN proper shipping name
IMDG: 2813
IATA: 2813
ADR/RID:
IMDG:
IATA:
WATER-REACTIVE SOLID, N.O.S. (Strontium nitride, powder)
WATER-REACTIVE SOLID, N.O.S. (Strontium nitride, powder)
Water-reactive solid, n.o.s. (Strontium nitride, powder)
14.3
Transport hazard class(es)
14.4
14.5
14.6
15.
ADR/RID: 4.3
Packaging group
ADR/RID: II
Environmental hazards
ADR/RID: no
Special precautions for user
no data available
REGULATORY INFORMATION
IMDG: 4.3
IMDG: II
IMDG Marine pollutant: no
IATA: 4.3
IATA: II
IATA: no
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1
15.2
16.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available
OTHER INFORMATION
Further information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.


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